Name | methylhexahydrophthalic anhydride |
Synonyms | MHHPA MeHHPA 1. Methyl Hexahyd Methylhexahydrophthalic anhydrid methylhexahydrophthalic anhydride Hexahydromethylphthalsureanhydrid methyl hexahydrophthalic anhydride hexahydromethyl-1,3-Isobenzofurandione 3,4-Methyl hexahydrophthalic anhydride 1,3-Isobenzofurandione, hexahydromethyl- 3a-methylhexahydro-2-benzofuran-1,3-dione methyl hexahydrophthalic anhydride (MHHPA) 1. Methyl Hexahydrophthalic Anhydride (MHHPA) HEXAHYDROMETHYLPHTHALIC ANHDRIDE, MIXTURE OF ISOMERS 2,2'-(oxydicarbonyl)bis(2-methylcyclohexanecarboxylic acid) methyl-1,2-cyclohexanedicarboxylic anhydride mixture of isomers |
CAS | 25550-51-0 |
EINECS | 247-094-1 |
InChI | InChI=1/C18H26O7/c1-17(9-5-3-7-11(17)13(19)20)15(23)25-16(24)18(2)10-6-4-8-12(18)14(21)22/h11-12H,3-10H2,1-2H3,(H,19,20)(H,21,22) |
Molecular Formula | C9H12O3 |
Molar Mass | 168.19 |
Density | 1.162 |
Boling Point | 299℃[at 101 325 Pa] |
Flash Point | 195.1°C |
Vapor Presure | 0.274Pa at 25℃ |
Appearance | Transparent liquid |
pKa | 4.12[at 20 ℃] |
Storage Condition | Inert atmosphere,Room Temperature |
Refractive Index | 1.479Nd(25°C) |
Physical and Chemical Properties | Colorless transparent liquid. |
Use | Used as curing agent for epoxy resin |
Safety Description | 24/25 - Avoid contact with skin and eyes. |
HS Code | 29329990 |
LogP | 2.59 at 25℃ |
EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
use | is an excellent organic solvent with a wide range of uses. it is mainly used as a solvent for oil and fat, an extractant, an electrolytic solvent for lithium batteries, a chlorine-based solvent stabilizer, a pharmaceutical intermediate and a raw material for copolyformaldehyde. it can also be used as a raw material for silk finishing agent and sealing glue as a curing agent for epoxy resin |
production method | (1) maleic anhydride and 1,3-pentadiene are added to a stirring reactor, and heated under stirring to carry out diene addition reaction to generate methyl tetrahydrophthalic anhydride: (2) continuous hydrogenation of methyl tetrahydrophthalic anhydride to produce methyl hexahydrophthalic anhydride by continuous hydrogenation of methyl tetrahydrophthalic anhydride adopts a continuous trickle bed reaction process, and the optimized reaction process parameters are: inlet temperature 185 ℃, pressure 7.0MPa, hydrogen-oil ratio 3000: 1. The total conversion rate of the product is about 98.2%, and the total yield of the product is 85.8%. The catalytic hydrogenation reaction formula of methyltetrahydrophthalic anhydride is as follows: |